Photographic & Sensitive Products

tio2 rutile titanium dioxide R996 hs code: 3206111000

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Specifications:

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Liangjiang?brand-rutile?titanium?dioxide?R996,?adopt?ZrO?and?Al2O3?as?inorganic?coatings?materials.?

Make?surface?modification?with?organic?treating?agent.?And?it?has?better?whiteness,?better?dispersibility.?

Mainly?used?in?solvent?based?coating,?emulsion?varnish,?industrial?paints,?print?ink,?plastic?and?other?fields.

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product?application:

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Mainly?used?in?solvent?based?coating,?emulsion?varnish,?industrial?paints,?print?ink,?plastic?and?other?fields.

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main?feature:

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High?gloss,?easily?to?be?wet?and?dispersibility,?better?weather?fastness,?light?resistance,?

widely?used?in?many?fields.

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Basic?data:

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?Item | ?titanium?dioxide(TiO2) |
CAS?NO. | 13463-67-7 |
EINECS?NO. | 236-675-5 |
color?indexing | 77891,?white?pigments |
ISO591-1:2000 | R2 |
ASTM?D476-84 | III,?IV |
?Appearance | ?white?powder |
true?specific?gravity | 4.0?g/cm3 |
apparent?density | 0.7~1.0?g/cm3 |
?surface?treatment | Coated?with?Zr?and?Al?+?special?organic?treatments |
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Typical?technical?index(?Standard:Q/VAIP1-2010)

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Index | R-996 |
inorganic?surface?treatment | ZrO2,,AL2O3 |
organic?surface?treatment | ?yes |
TiO2?content?% | ≥93 |
lightness?% | ≥98 |
Tint?reducing?power | ≥1900 |
105℃?volatile?matter?% | ≤0.5 |
water?soluble?matter?% | ≤0.5 |
?PH?value | 6.5～8.5 |
?oil?absorption???(g/100g) | ≤22 |
electrical?resistivity??Ωm | ≥100 |
?residue?on?45um?sieve?% | ≤0.1 |
rutile?content?????% | ≥98.0 |
?white?degree?(?compared?with?standard?sample) | ?not?less |
High?stirring?dispersion?in?Alkyd?system?μm | ≤35 |
Enterprise?internal?control?Index (Dry?powder,?hue?value) | ?L*?(samples-?standard?samples)? | ≥98 |
?b | ≤2.0 |
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Description:

1,?Liangjiang Brand?rutile titanium dioxide?R996?is manufactured through sulfuric acid process,?using?high-quality titanium ore?as the main raw material,?get finished products after acidolysis,?hydrolysis, calcine,? and?surface treatment.

has compact crystal structure, and it is stable in light, so it has better weather fastness,

water resistence, and not easily to become yellow. It also has better hiding power, reducing power.

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Sulfuric acid process rutile titanium dioxide

Advantage: take low-cost titanium ore ( or titanium slag ) and sulfuric acid as materials, long-standing technology, ripe technique, lower producing cost.

Disadvantage:? more process, longer technological process, seriously environmental pollution, normal quality stability, lower quality.

Chlorination process rutile titanium dioxide

Advantage: take high-purity artificial rutile (TiO2≥90%) as material, shorter technological process, easily to expand producing capacity, higher quality, can be used as substitute of imported chlorination titanium dioxide.

Disadvantage: Currently, chlorination process titanium dioxide is monaplized by oversea companies, difficulty to import oversea equipments and technology. Higher cost caused by taking high-purity titanium ore as material. More difficulty technology.

Titanium dioxide, TiO2, CAS number: 13463-67-7, EINECS number: 236-675-5, English name is titanium dioxide, formula is TiO2, MW 79.90. Also called titanium white. Titanium dioxide exist in titanium ore and rutile ore. Its high lightness and hiding power resulted from its structure.

Due to the different raw materials and production process, the product performance is different and has different requirements to the weather resistance, hiding power, aesthetics and dispersion titanium dioxide. So the clients should choose titanium dioxide of different quality based on their needs.

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2,?Titanium dioxide compared with other kinds of white pigment :

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Pigment name | Relative density | Reflactive index | ?tinting reducing power | Hiding power |
Reynolds number | Relative value |
Chlorination rutile TiO2 | 4.0 | 2.85 | 1800 | 105 | 105 |
Sulfuric acid process TiO2 | 4.2 | 2.76 | 1650 | 100 | 100 |
Anatase TiO2 | 3.91 | 2.55 | 1270 | 77 | 78 |
Barium sulfate | 4.5 | 1.64 | ? | ? | ? |
Zinc oxide | 5.6 | 2.02 | 200 | 12 | 14 |
Lithopone | 4.2 | 1.84 | 260 | 16 | ? |
Basic lead carbonate | 6.1 | 2 | 150 | 9 | 12 |
Zinc sulfate | 4 | 2.37 | 660 | 40 | 39 |
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From this sheet, Liangjiang brand rutile titanium dioxide, chlorination process and sulfuric acid process, both has highest coefficient of refraction, highest covering power and tint reducing power. Higher whiteness, higher gloss and better dispersibility.

5.?Titanium dioxide anatase, titanium dioxide antase coated, titanium dioxide rutile sulfuric process, titanium dioxide rutile chlorination process:

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? | Anatase TiO2 | Coated Anatase Tio2 | Sulfuric acid process rutile Tio2 | Chloride process rutile TiO2 |
powder | Indoor powder | Indoor powder | Indoor/outdoor powder | Indoor/outdoor powder |
Usage amount | large | little | large | less |
Dispersibility | bad | good | good | good |
Covering power | bad | bad | good | better |
Surface properties | bad | good | good | Good |
liquidity | bad | good | good | good |
Yellowing resistance | bad | bad | good | better |
Color stability | bad | normal | good | better |
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Coatings industry consumes most qty of titanium dioxide, especially the rutile type. The global coating industries occupy 58% - 60%, mainly because the aspects of the performance is much better than the other white pigments. So the coating using by titanium dioxide is much higher than ordinary filler, because titanium dioxide is an integral part of in the coating, covering and adornment, its role is not only more important is to improve the physical and chemical properties of paint, bust also to improve the mechanical strength of the coating, adhesion, anticorrosive, light and weather resistance.So during of the production of coatings, It’s reasonable for us to choose the suitable type and specs!

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Applications:

1. Characteristic?requirements?for?titanium?dioxide?in?coatings?and?paints

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Item | ?Building Coat |
Normal temperature drying enamel paint (Little porcelain paint type) | emulsion coatings? |
Outdoor | weather resistance, Hiding power, aesthetic property | weather resistance, Hiding power, aesthetic property( Little outdoor) |
Indoor | Hiding power, aesthetic property | Hiding power, aesthetic property |
item | ?Industrial Coat |
automobile | home electrical appliances? |
Finish coat | weather resistance, Hiding power, aesthetic property , dispersibility | Hiding power, aesthetic property |
floating coat | weather resistance, Hiding power, dispersibility |
primer coat | dispersibility |
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Coatings industry consumes most qty of titanium dioxide, especially the rutile type. The global coating industries occupy 58% - 60%, mainly because the aspects of the performance is much better than the other white pigments. So the coating using by titanium dioxide is much higher than ordinary filler, because titanium dioxide is an integral part of in the coating, covering and adornment, its role is not only more important is to improve the physical and chemical properties of paint, bust also to improve the mechanical strength of the coating, adhesion, anticorrosive, light and weather resistance.So during of the production of coatings, It’s reasonable for us to choose the suitable type and specs!

2. Titanium dioxide quality requirements for plastic, PVC and masterbatch

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Item | ?Performance |
Hiding power | Lighter and thinner plastic products can be produced using tio2 of good hidinding power |
Whiteness | Decide the appearance of the white or light color palstic products light color or white color |
Dispersibility | Affect the production cost of plastic products as bad dispersibility affects the? smoothness and brightness |
Weather resistance | The outdoors plastic products and plastic doors and windows require the weather resistance of tio2 |
Machinability | Titanium dioxide machinability is the vital key to the production efficiency and cost in the production of white masterbatch (especially the concentration variety) |
Performace impact | Titanium dioxide volume of addition can affects the quality of the plastic products, especially in the condition of larger addition |
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Plastic is the second largest parts for titanium dioxide, occupying about 20% of the total world titanium dioxide demands, There are more than 50 brands belongs to plastic specials in the world 500 barands. Requirements for plastic, fine particle, good dispersion performance;Good heat resistance and light resistance,During the heat and the plastic forming process , the finished product does not change color in sunlight exposure and use process. Most of the particle size in plastic is fine. In the plastics, to join titanium dioxide

can improve the heat resistance of plastic products, light fastness, weather resistance, make the plastic products to improve the physical and chemical performance.The strong mechanical strength can extend their life!

The effect of titanium pigment in the plastics industry mainly has two aspects, one is used as the basic white pigment, provide cover (white color); the second is to block uv light, used as uv screen disadvantages agent, used for outdoor plastic products to provide a good weatherability. For the Common plastic,it does not require the weatherability, focuses More on the paint performance requirements.

Due to the characteristics of palstic products, When choosing different, should be taken into account in accordance with the technical requirements of plastic products, mainly to choose anatase or rutile, not same as the coatings, inks, paints.

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3. Titanium dioxide quality requirements for paper production:

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classification | Tio2 classification | remark |
Rutile | Anatase |
decorative paper | √ | ? | Higher Anti-aging requirement |
High ash paper | √ | ? | Better Hiding power |
Low ash paper | ? | √ | Better opacity |
coinage paper | ? | √ | Better opacity |
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Paper is the third largest parts for titanium dioxide, As the paper filter, mainly use in high grade paper and thin paper. To join titanium dioxide in the paper can make the paper good whiteness, good gloss, high strength, thin and smooth, not penetrate when printing, light quality.Titanium dioxide for Paper generally use the titanium dioxide without the surface treatment, can have the effect of fluorescent whitening agent, increase the whiteness of paper, but laminated paper use requires the surface treatment of rutile titanium, to meet the requirements of light resistance and heat resistance.

Different paper use, different type titanium dioxide, titanium dioxide rutile, good oxidation resistance good weather resistance, mainly used for decorative paper and high ash paper of weather resistance; While titanium dioxide anatase used for the low transparency and low ash paper,not high rquirement for? weather resistance.Although chlorination process and sulfuric acid process can produce rutile type, but the chlorination process titanium pigment , whiteness, the red crystal type of content, especially the stability of the finished product is better than that of the sulfuric acid method, suitable for use in the decorative paper and high ash;And coinage in the paper and the low ash must be used titanium dioxide by sulfuric acid, in order to meet the requirements of opacity for two kinds of paper.

4. Titanium dioxide quality requirements for ink and rubber :

Titanium dioxide , also have a wide range of applications in ink,rubber and others, including the three major application fields.

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?(1) Ink

Titanium dioxide is an indispensable white pigment in the senior ink, ink containing titanium dioxide color fast, good surface moisture resistant, easy to disperse, rutile type titanium pigment,both used in the printing ink industry .
Practice proved rutile type titanium pigment has ideal application performance, can be widely used in various types of ink preparation, crystal shape, refractive index and tinting strength, the index of fluorescence, type is better than the sharp titanium rutile type titanium pigment, therefore, rutile type titanium pigment is widely used in printing ink.

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